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Peach performing the move against Bowser in Super Smash Bros. Brawl.
The Toad move in the Super Smash Bros. series will cause Princess Peach to pull out Toad, a character and species from the Super Mario series, and basically use him as a shield, though unlike a regular shield he'll only stay out for a second. Toad will also deliver health to Princess Peach if he manages to block a projectile such as a Missile.
It should also be noted that this is Kirby's copy ability if he Inhales Peach.